I used to hate anime music, it was so cheesy. Though I love Urusei Yatsura and Ranma 1/2, the music is abominable. Boy has it gotten better since the 90's.
Tank! by Yoko Kano and The Seatbelts from
Cowboy Bebop
Rise by Yoko Kano from
Ghost in the Shell Stand Alone Complex
Ride on Shooting Star by The Pillows from
FLCL
Hare Hare Yukai by Aya Hirano from
The Melancholy of Haruhi Suzumiya